Copied & pasted from wikipedia's bio on Evgeni Plushenko:
The first skater in the world to perform a quadruple toe loop-triple toe loop-double loop jump (4–3–2) combination in competition, at the 1999 NHK Trophy (he has since landed his 4–3–2 combination 26 times so far). He is the first skater to have landed a quadruple toe loop-triple toe loop-triple loop (4–3–3) combination in competition, at the Cup of Russia 2002 (he has since landed his 4–3–3 combination four times so far). Plushenko is also the first skater to land a triple toe loop-triple toe loop-triple loop-double loop (3–3–3–2) combination, which was at the 2005 "Ard Gala". At the European Championships, he landed a six jump combination (3–3–2–2–2–2) in his exhibition program. He has landed a four jump combination; 4 toe loop-3 toe loop-2 loop-2 loop, at the World Championships in 2001. Plushenko has landed a consistent quadruple toe loop in competition, and has also landed a quadruple salchow in Samara, Russia at the 2004 "Second stage of Cup of Russia". It is estimated that he has landed a total of about 100 quads in competition.